Spatial and temporal variability in particle-bound pesticide exposure and their effects on benthic community structure in a temporarily open estuary     

S. Bollmohr  P.J. van den Brink  P.W. Wade  J.A. Day  R. Schulz 《Estuarine, Coastal and Shelf Science》2009

Spatial and temporal variations in particle-bound pesticide contamination, natural environmental variables, and benthic abundance were measured during the dry summer season within a temporarily open estuary (Lourens River). This study focused on the effect of particle-associated pesticides on the dynamics of the benthic community (including epi-benthic, hyper-benthic, and demersal organisms) by comparing two runoff events, differing in their change in pesticide concentration and environmental variables. The two chosen sites were situated within the upper and middle reaches of the estuary and differ significantly in salinity (p = 0.001), flow (p = 0.5), temperature (p < 0.001) and particulate organic carbon in the sediment (p < 0.001). Generally higher particle-bound pesticides were found in the upper reaches.  相似文献   

On modelling the effects of afforestation on acidification in heterogeneous catchments at different spatial and temporal scales     

A. J. Wade  C. Neal  C. Soulsby  S. J. Langan  R. P. Smart 《Journal of Hydrology》2001,250(1-4):149-169

A modelling approach is presented for simulating and predicting future changes in streamwater Gran alkalinity throughout a large, heterogeneous river system. The methodology is based on integrating End Member Mixing Analysis (EMMA), the Model of Acidification of Groundwater in Catchments (MAGIC) and spatial data describing the catchment characteristics stored on a Geographical Information System (GIS). These are integrated within a Functional Unit Network (FUN) to predict the changes in Gran alkalinity resulting from possible future changes in atmospheric deposition and land use (low intensity afforestation) in the River Dee catchment, NE Scotland. Model results indicate that declining sulphate and constant nitrogen deposition, combined with low intensity Scots pine (Pinus sylvestris) afforestation are unlikely to contribute significantly to streamwater acidification.  相似文献   

Sources and bioavailability of polynuclear aromatic hydrocarbons in Galveston Bay, Texas     

Yaorong Qian  Terry L. Wade  Jose L. Sericano 《Estuaries and Coasts》2001,24(6):817-827

Oyster and sediment samples collected from six sites in Galveston Bay from 1986 to 1998 were analyzed for polynuclear aromatic hydrocarbons (PAHs). Total concentrations of parent PAHs in oysters ranged from 20 ng g⁻¹ at one site to 9,242 ng g⁻¹ at another and varied randomly with no clear trend over the 13 year period at any site. Concentrations of alkylated PAHs, which are indications of petroleum contamination, varied from 20 to 80,000 ng g⁻¹ in oysters and were in higher abundance than the parent PAHs, indicating that one source of the PAH contaminants in Galveston Bay was petroleum and petroleum products. Four to six ring parent PAHs, which are indicative of combustion source , were higher than those of 2–3 ring parent PAHs, suggesting incomplete combustion generated PAHs was another source of PAHs into Galveston Bay. Concentrations of parent PAHs in sediments ranged from 57 to 670 ng g⁻¹ and were much lower than those in oysters. Sediments from one site had a high PAH concentration of 5,800 ng g⁻¹. Comparison of the compositions and concentrations of PAHs between sediment and oysters suggests that oysters preferentially bioaccumulate four to six ring PAHs. PAH composition in sediments suggests that the sources of PAH pollution in Galveston Bay were predominantly pyrogenic, while petroleum related PAHs were secondary contributions into the Bay.  相似文献   

A second look at the method of random walks     

Wade E. Hathhorn 《Stochastic Environmental Research and Risk Assessment (SERRA)》1996,10(4):319-329

A formal statistical discussion of the origins of the random walk and its relation to the classic advection-dispersion equation is given. At issue is the common use of Gaussian distributed steps in producing the desired dispersive effects. Shown are alternative solutions to the basic Langevin equation describing mass displacements based on non-Gaussian, white increments. In particular, the results reveal that uniform or symmetric-triangular steps can be employed without loss of generality in accuracy of the solution (over all Peclet numbers) and may yield significant savings in the computational generation of the random deviates required in the Monte Carlo procedures of the random walk method.  相似文献   

Preliminary results of improved model fits to the extreme and far UV observations of cataclysmic variables     

T. E. Carone  R. S. Polidan  R. A. Wade 《Astrophysics and Space Science》1987,130(1-2):239-242

We present the first results of a study which will attempt to analyze the combined Voyager and IUE observations of cataclysmic variables using steady-state accretion disk models. Initially we use flux ratio diagrams to determine if a combination of models will suffice or if new ingredients are necessary.Paper presented at the IAU Colloquium No. 93 on Cataclysmic Variables. Recent Multi-Frequency Observations and Theoretical Developments, heald ar Dr. Remeis-Sternwarte Bamberg, F.R.G., 16–19 June, 1986.  相似文献   

Cloning and analysis of the CYP1A promoter from the atlantic killifish (Fundulus heteroclitus)     

Powell WH  Morrison HG  Weil EJ  Karchner SI  Sogin ML  Stegeman JJ  Hahn ME 《Marine environmental research》2004,58(2-5):119-124

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KPD 0422 + 5421: a new short-period subdwarf B/white dwarf binary     

C. Koen  Jerome A. Orosz  & Richard A. Wade 《Monthly notices of the Royal Astronomical Society》1998,300(3):695-704

The subdwarf B (sdB) star KPD 0422 + 5421 was discovered to be a single-lined spectroscopic binary with a period of P  = 0.090 1795 ± (3 × 10⁻⁷) d (2 h 10 min). The U B light curves display an ellipsoidal modulation with amplitudes of ≈ 0.02 mag. The sdB star contributes nearly all of the observed flux. This and the absence of any reflection effect suggest that the unseen companion star is small (i.e. R _comp ≈ 0.01 R_⊙) and therefore degenerate. We modelled the U B light curves and derived i  = 78.05° ± 0.50° and a mass ratio of q  =  M _comp/ M _sdB = 0.87 ± 0.15. The sdB star fills 69 per cent of its Roche lobe. These quantities may be combined with the mass function of the companion [ f ( M ) = 0.126 ± 0.028 M_⊙] to derive M _sdB = 0.72 ± 0.26 M_⊙ and M _comp = 0.62 ±  0.18 M_⊙. We used model spectra to derive the effective temperature, surface gravity and helium abundance of the sdB star. We found T _eff = 25 000 ± 1500 K, log g  = 5.4 ± 0.1 and [He/H] = −1.0. With a period of 2 h 10 min, KPD 0422 + 5421 has one of the shortest known orbital periods of a detached binary. This system is also one of only a few known binaries that contain a subdwarf B star and a white dwarf. Thus KPD 0422 + 5421 represents a relatively unobserved, and short-lived, stage of binary star evolution.  相似文献   

Residence time of non-methane hydrocarbons in the atmosphere     

A. Duce  G. Quinn  L. Wade 《Marine pollution bulletin》1974,5(4):59-61

Little is known about the atmospheric distribution and residence time of hydrocarbons, although this is critical in evaluating their impact on the oceans. This paper reviews the sparse data on both global production and concentration of atmospheric hydrocarbons in marine and continental non-urban areas, and estimates the atmospheric residence time of these substances.  相似文献   

Thermodynamics of U(VI) sorption onto Shewanella putrefaciens     

Johnson R. Haas  Thomas J. Dichristina  Roy Wade  Jr. 《Chemical Geology》2001,180(1-4):33-54

We have conducted acid–base potentiometric titrations and U(VI) sorption experiments using the Gram negative, facultatively anaerobic bacterium Shewanella putrefaciens. Results of reversed titration studies on live, inactive bacteria indicate that their pH-buffering properties result from the equilibrium ionization of three discrete populations of functional groups. Carboxyl (pK_a=5.16±0.04), phosphoryl (pK_a=7.22±0.15) and amine (pK_a=10.04±0.67) groups most likely represent these three resolvable functionalities, based on their pK_a values. Site densities for carboxyl, phosphoryl and amine groups on the bacterial surface were approximately 31.7 μmol sites/g bacteria (0.35±0.02 sites/nm²), 8.95 μmol/g (0.11±0.007 sites/nm²) and 38.0 μmol/g (0.42±0.008 sites/nm²), respectively, based on an estimated bacterial specific surface area of 55 m²/g. Sorption experiments showed that U(VI) can reversibly complex with the bacterial surface in the pH 2–8 interval, with maximum adsorption occurring at a pH of 5. Sorption is not strongly sensitive to ionic strength (NaCl) in the range 0.02–0.10 M. The pH and ionic strength dependence of U(VI) sorption onto S. putrefaciens is similar to that measured for metal-oxide surfaces and Gram positive bacteria, and appears to be similarly governed by competitive speciation constraints. Measured U(VI) sorption is accounted for by using two separate adsorption reactions forming the surface complexes >COO–UO₂⁺ and >PO₄H–UO₂(OH)₂. Using S. putrefaciens as a model organism for dissimilatory metal-reducing Gram negative anaerobes, our results extend the applicability of geochemical speciation models to include bacteria that are capable of reductively solubilizing or precipitating a wide variety of environmentally and geologically important metals and metallic species.  相似文献   

Tidal river sediments in the Washington,D.C. area. I. Distribution and sources of trace metals     

David J. Velinsky  Terry L. Wade  Christian E. Schlekat  Beth L. McGee  B. J. Presley 《Estuaries and Coasts》1994,17(2):305-320

Thirty-three bottom sediments were collected from the Potomac and Anacostia rivers, Tidal Basin, and Washington Ship Channel in June 1991 to define the extent of trace metal contamination and to elucidate source areas of sediment contaminants. In addition, twenty-three sediment samples were collected directly in front of and within major storm and combined sewers that discharge directly to these areas. Trace metals (e.g., Cu, Cr, Cd, Hg, Pb, and Zn) exhibited a wide range in values throughout the study area. Sediment concentrations of Pb ranged from 32.0 μg Pb g^?1 to 3,630 μg Pb g^?1, Cd from 0.24 μg Cd g^?1 to 4.1 μg Cd g^?1, and Hg from 0.13 μg Hg g^?1 to 9.2 μg Hg g^?1, with generally higher concentrations in either outfall or sewer sediments compared to river bottom-sediments. In the Anacostia River, concentration differences among sewer, outfall, and river sediments, along with downriver spatial trends in trace metals suggest that numerous storm and combined swers are major sources of trace metals. Similar results were observed in both the Tidal Basin and Washington Ship Channel. Cadminum and Pb concentrations are higher in specific sewers and outfalls, whereas the distribution of other metals suggests a more diffuse source to the rivers and basins of the area. Cadmium and Pb also exhibited the greatest enrichment throughout the study area, with peak values located in the Anacostia River, near the Washington Navy Yard. Enrichment factors decrease in the order: Cd>Pb>Zn>Hg>Cu>Cr. Between 70% and 96% of sediment-bound Pb and Cd was released from a N₂-purged IN HCl leach. On average, ≤40% of total sedimentary Cu was liberated, possibly due to the partial attack of organic components of the sediment. Sediments of the tidal freshwater portion of the Potomac estuary reflect a moderate to highly components area with substantial enrichments of sedimentary Pb, Cd, and Zn. The sediment phase that contains these metals indicates the potential mobility of the sediment-bound metals if they are reworked during either storm events or dredging.  相似文献